I'm fairly new to playing and was wondering when I can use Outwit. Here is an example to help me explain.

I'm using R Mysterio with E Annihilus. Can I taxi Mysterio within the 10 range, outwit the targets defense, and then hit with Annihilus' Running Shot attack? And, if Mysterio has taken 1 damage already, could he then attempt to MC someone?

Thanks for the help!

Two things keep this from happening.

First, you can't use Outwit during another action, so if Annihilus uses the first part of his running shot to taxi Mysterio, he needs to complete his action (i.e the attack portion of running shot), before Mysterio can use the free action of Outwit.

Mysterio could not Mind Control on the same turn as being taxied, as it requires an action (non-free) and that is prohibited by the rules. He must wait until the next turn before taking any non-free action.

-Hope that helps.

Doh! Forgot about NAAT in this case. This definitely helps.

On a related MC issue - if I MC someone with Imp, can I have them turn off Imp AND do something else?

Yes.

Excellent - thanks for the help!